TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preferred Components: The metal cation comprises zinc ion, (Zn2+), cadmium ion (Cd2+), copper ion (Cu2+), manganese ion (Mn2+), cobalt ion (Co2), nickel ion (Ni2+). The dcx is an anion comprises 1,4-benzenedicarboxylic acid, substituted 1,4-benzenedicarboxylic acid of formula (2), 1,4-cyclohexanedicarboxylic acid, 2,6-naphthalenedicarboxylic acid, biphenyl-4,4'-dicarboxylic acid, thiophene-2,5-dicarboxylic acid, and 2,5-dihydroxyterephthtalic acid. The hydrazone L comprises substituted benzoic acid (1-phenyl-methylidene)-hydrazide of formula (8), substituted benzoylhydrazino methyl phenyl methylenebenzohydrazide of formula (9) or substituted benzoylhydrazino methyl phenyl methylenebenzohydrazide of formula (10). The coordination polymers comprise at least one type of guest molecule. The guest molecules are molecules of a solvent. The molecules of a solvent comprises water, N,N'-dimethylformamide, N,N'-diethylformamide, or 1-8 carbon alcohol. The guest molecules are molecules of a gas. The gas molecules comprise nitrogen, hydrogen, carbon dioxide, carbon monoxide, argon, nitrogen monoxide, or nitrogen dioxide. The gas molecules comprise 1-6 carbon alkanes, 2-6 carbon alkenes, 2-6 carbon alkynes, 6-8 carbon arenes, or 1-8 carbon alcohols. The coordination polymers do not contain guest molecules. The compound of aldehyde or ketone group comprises substituted benzaldehyde of formula (11), benzene-1,4-dicarbaldehyde or benzene-1,3-dicarbaldehyde. The hydrazide is substituted benzoic acid hydrazide of formula (14). The solvent comprises 1-8 carbon alcohol, an aqueous alcoholic solution, N,N'-dimethylformamide (DMF), or N,N'-diethylformamide (DEF). The metal compound comprises M(NO3)2, M(ClO4)2, M(SO4)2, M(CH3COO)2 or MCl2. The dicarboxylic acid comprises 1,4-benzenedicarboxylic acid, (2), 1,4-cyclohexanedicarboxylic acid, 2,6-naphthalenedicarboxylic acid, biphenyl-4,4'-dicarboxylic acid, thiophene-2,5-dicarboxylic acid, or 2,5-dihydroxyterephthtalic acid. The molecules comprise water, carbon dioxide, carbon monoxide, alcohols, water, and hydrocarbon. The ionic conductors comprise hydrogen ion (H+), lithium ion (Li+), sodium ion (Na+), potassium ion (K+), ammonium ion (NH4+).X = NH2, Br, NO2, OH;A, D, X, z = N, CNH2, or CH; andR = H, 1-6C alkyl or aryl.Preferred Method: The method further comprises step two of reacting condensation product using a metal compound and a dicarboxylic acid. The condensation reaction is conducted by mechanochemical means, i.e. in the absence or with a small participation of a solvent. The condensation reaction is conducted with the addition of 1-2 drops of sulfuric (VI) acid. The condensation reaction is conducted in a solvent. The both steps of the synthesis are conducted within a temperature -20 degrees C to 150 degrees C. The synthesis are conducted under autogenous pressure, in a closed vessel. EXAMPLE - 686 mg Isonicotinic acid hydrazide was dissolved in 20 cm3 of ethanol. 0.471 cm3 4-picolinic aldehyde was added and the mixture was heated to reflux for 20 minutes. Subsequently the solution was left to cool and crystallize the product. After the crystallization the precipitate was filtered, and the filtrate was concentrated and left in ice bath until the crystallization of a further product fraction. The second crystallized fraction was filtered. The fractions were combined and air-dried. 453 mg Hydrazone L, 332 mg 1,4-benzenedicarboxylic acid were dissolved in 162 cm3 of N,N'-dimethylformamide (DMF) and 18 cm3 of water. The sealed vessel was heated at 70 degrees C for 48 hours to yield a 420 mg fine-crystalline yellow product. The product was washed with DMF and dried in a vacuum oven. The product was identified using elemental, spectral, crystallographic, diffractometric and thermogravimetric analysis.