TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - Preferred Components: The second catalyst is dibutyltin oxide and/or dibutyltin acetate. The catalyst is: zinc(II) acetylacetonate, zinc(II) 2-ethylhexanoate, zinc(II) triflate, zinc(II) trifluoroacetate hydrate, zinc(II) 2-mercaptopyridine-N-oxide, zinc(II) bis(2,2,6,6-tetramethyl-3,5-heptanedionate), zinc(II) toluenesulfonate, zinc(II) dibutyldithiocarbamate, zinc(II) hexafluoroacetylacetonate, zinc oxides, zinc halides, zinc hydroxide, and/or zinc halide hydroxide; or calcium(II) acetylacetonate, calcium(II) 2-ethylhexanoate, calcium(II) bis(trifluoromethanesulfonate), calcium carbonate, calcium stearate, calcium perchlorate, calcium halides, calcium hydroxide, calcium methoxide, calcium ethoxide, calcium isopropoxide, and/or calcium(II)oxide; or magnesium(II) acetylacetonate, magnesium(II) 2-ethylhexanoate, magnesium(II) bis(trifluoromethanesulfonate), magnesium carbonate, magnesium stearate, magnesium perchlorate, magnesium halides, magnesium hydroxide, magnesium ethoxide, magnesium butoxide, and/or magnesium(II) oxide.    TECHNOLOGY FOCUS - POLYMERS - Preferred Process: A second catalyst comprising carbamylation catalysts is present. Preferred Definitions:    M = Mn(II), Zn(II), Ca(II), Mg(II), Pb, Co, or Ba(II); and    Z = anionic functionalities (ligands) comprising 2-ethylhexanoate, benzoate, hexafluoroacetylacetonate, isopropoxide, acetyl acetonate, phenoxide, 2-mercaptopyridine-N-oxide, toluenesulfonate, stearate, tert-butoxide, neodecanoate, citrate, trifluoromethanesulfonate, n-butoxide, trifluoroacetate, dibutyldithiocarbamate, 1,1,1-trifluoro-2,4-pentanedionate, 2,2,6,6-tetramethyl-3,5-hexanedionate, cresylate, ethoxide, methoxide, triethanolaminato, 2-methyl-2-butoxide, oxo, F, Cl, Br, I, or other anionic functionalities capable of binding to a trivalent metal.    EXAMPLE - 785.93 g of Paraloid AU-608X (RTM: Hydroxyl-functional acrylic polyol) comprising 58% of solid and 42% of solvent (such as xylenes) was added to a reactor, which had 0.70 mole hydroxyl functionality. 5.04g zinc acetylacetonate (99% pure) was added to the reactor. The heating mantle was started and set at 158 degrees C. The nitrogen sparging flow rate was set at 20 sccm. The reaction mixture was agitated at 100 revolutions per minute and then adjusted to 400 revolutions per minute when the reactor temperature was over 60 degrees C. 42.41 g of 99% pure urea was dissolved in 39.31 g of deionized water to form aqueous solution. When the reactor temperature reached 138 degrees C, the urea aqueous solution was fed into the reactor using a syringe pump and the reaction timer was started. The aqueous urea solution was fed at 2 ml/minute for 10 minutes and then decreased to 5 ml/hour. The total feeding time was 10 hours. Once the feeding of urea was done, the reaction continued until the total reaction time reached 20 hours. The reaction was carried out at 138-142 degrees C. After the reaction was complete, the heating mantle was shut down and the agitation rate was reduced to 60 revolutions per minute. When the reactor temperature dropped to 60 degrees C, the polycarbamate product was poured out from the reactor.